NCERT Solutions for Class 11 Physics Chapter 1: Units and Measurement
Complete, topper-style NCERT Solutions for Class 11 Physics Chapter 1 Units and Measurement (2026-27 reprint): full revision notes on SI units, significant figures, dimensions and dimensional analysis, plus step-by-step answers to all 17 exercise questions (1.1–1.17) with calculations, diagrams and exam tips.
Chapter at a glance — complete revision notes
1.1 Introduction
Measurement of a physical quantity means comparing it with an internationally accepted reference standard called a unit. A result is always expressed as a number (numerical measure) accompanied by a unit: ‘length = 5 m’ has no meaning without ‘m’. Although physical quantities are very numerous, they are inter-related, so a small number of units is enough to express all of them.
- Fundamental (base) quantities and base units: a limited set of independent quantities and their units (e.g. length → metre, mass → kilogram, time → second).
- Derived quantities and derived units: all other quantities, whose units are combinations of the base units (e.g. speed → m s−1, force → kg m s−2).
- System of units: the complete set of base units and derived units.
1.2 The International System of Units
Earlier, different countries used different systems: CGS (centimetre, gram, second), FPS or British (foot, pound, second) and MKS (metre, kilogram, second). The system now accepted internationally is the Système International d’Unités (SI), developed by the Bureau International des Poids et Mesures (BIPM) in 1971 and revised by the General Conference on Weights and Measures in November 2018. Because it is a decimal system, conversions are simple. It has seven base units (Table 1.1) and two supplementary dimensionless units: the radian (plane angle dθ = ds/r) and the steradian (solid angle dΩ = dA/r2).
| Base quantity | SI unit | Symbol | Definition (2018): the unit is fixed by giving this constant an exact value |
|---|---|---|---|
| Length | metre | m | Speed of light in vacuum c = 299 792 458 m s−1 (second defined through the caesium frequency) |
| Mass | kilogram | kg | Planck constant h = 6.62607015 × 10−34 J s |
| Time | second | s | Caesium-133 hyperfine transition frequency ΔνCs = 9 192 631 770 Hz |
| Electric current | ampere | A | Elementary charge e = 1.602176634 × 10−19 C |
| Thermodynamic temperature | kelvin | K | Boltzmann constant k = 1.380649 × 10−23 J K−1 |
| Amount of substance | mole | mol | Exactly 6.02214076 × 1023 elementary entities (Avogadro constant NA); the entities (atoms, molecules, ions, electrons …) must be specified |
| Luminous intensity | candela | cd | Luminous efficacy Kcd of radiation of frequency 540 × 1012 Hz = 683 lm W−1 |
NCERT note: these exact values need not be remembered; they only show the accuracy of measurement. Source: NCERT Table 1.1, PDF page 2 ↗
Units retained for general use (Table 1.2, outside SI)
| Name | Symbol | Value in SI unit |
|---|---|---|
| minute | min | 60 s |
| hour | h | 60 min = 3600 s |
| day | d | 24 h = 86400 s |
| year | y | 365.25 d = 3.156 × 107 s |
| degree | ° | 1° = (π/180) rad |
| litre | L | 1 dm3 = 10−3 m3 |
| tonne | t | 103 kg |
| carat | c | 200 mg |
| bar | bar | 0.1 MPa = 105 Pa |
| curie | Ci | 3.7 × 1010 s−1 |
| roentgen | R | 2.58 × 10−4 C/kg |
| quintal | q | 100 kg |
| barn | b | 100 fm2 = 10−28 m2 |
| are | a | 1 dam2 = 102 m2 |
| hectare | ha | 1 hm2 = 104 m2 |
| standard atmospheric pressure | atm | 101325 Pa = 1.013 × 105 Pa |
SI prefixes (Appendix A2) and derived units with special names
| Prefix | Symbol | Factor | Prefix | Symbol | Factor |
|---|---|---|---|---|---|
| deca | da | 101 | deci | d | 10−1 |
| hecto | h | 102 | centi | c | 10−2 |
| kilo | k | 103 | milli | m | 10−3 |
| mega | M | 106 | micro | μ | 10−6 |
| giga | G | 109 | nano | n | 10−9 |
| tera | T | 1012 | pico | p | 10−12 |
| peta | P | 1015 | femto | f | 10−15 |
| exa | E | 1018 | atto | a | 10−18 |
| Quantity | Unit (symbol) | In base units |
|---|---|---|
| Force | newton (N) | kg m s−2 |
| Energy, work | joule (J) | kg m2 s−2 |
| Power | watt (W) | kg m2 s−3 |
| Pressure | pascal (Pa) | kg m−1 s−2 |
| Frequency | hertz (Hz) | s−1 |
| Charge | coulomb (C) | A s |
Guidelines (Appendix A7, A8): unit symbols are written in roman type, are not pluralised, carry no full stop, and a unit named after a person starts with a small letter when written in full (newton) but its symbol is capital (N).
1.3 Significant figures
Every measurement involves error, so the result must show its precision. The reported number includes all digits known reliably plus the first uncertain digit: these are the significant figures. Period 1.62 s: digits 1 and 6 are certain, 2 is uncertain: three significant figures. Length 287.5 cm: four. Quoting more digits than are significant is superfluous and misleading. A change of units does not change the number of significant figures (2.308 cm = 0.02308 m = 23.08 mm = 23080 μm: four each).
Rules for counting significant figures
- All non-zero digits are significant.
- Zeros between two non-zero digits are significant (wherever the decimal point is).
- For a number less than 1, zeros to the right of the decimal point but left of the first non-zero digit are not significant (0.002308 has four significant figures).
- Trailing zeros in a number without a decimal point are not significant (123 m = 12300 cm = 123000 mm: three significant figures).
- Trailing zeros in a number with a decimal point are significant (3.500 and 0.06900 have four each).
- The zero conventionally placed left of the decimal in 0.1250 is never significant.
- Exact numbers (such as the 2 in d = 2r, or n in t/n) and defined constants have infinite significant figures.
Scientific notation removes ambiguity: write every number as a × 10^b with 1 ≤ a < 10. All digits of a (including trailing zeros) are significant; the power of 10 is irrelevant. 4.700 m = 4.700 × 102 cm = 4.700 × 103 mm = 4.700 × 10−3 km: four significant figures in each. Order of magnitude: round a to 1 (if a ≤ 5) or to 10 (if 5 < a ≤ 10); the exponent of 10 is the order of magnitude. Earth’s diameter 1.28 × 107 m is of order 107 m; hydrogen atom 1.06 × 10−10 m is of order 10−10 m, so Earth is 17 orders of magnitude larger.
1.3.1 Arithmetic with significant figures
- Multiplication / division: the result keeps as many significant figures as the factor with the least significant figures. Density = 4.237 g / 2.51 cm3 = 1.69 g cm−3 (three). Light year = 3.00 × 108 × 3.1557 × 107 = 9.47 × 1015 m.
- Addition / subtraction: the result keeps as many decimal places as the number with the least decimal places. 436.32 g + 227.2 g + 0.301 g = 663.821 g → 663.8 g. 0.307 m − 0.304 m = 3 × 10−3 m (not 3.00 × 10−3).
1.3.2 Rounding off the uncertain digits
Drop the unwanted digit; if it is > 5 raise the preceding digit by 1, if < 5 leave it. If the dropped digit is exactly 5, make the preceding digit even: 2.745 → 2.74 (4 is even, left unchanged) and 2.735 → 2.74 (3 is odd, raised by 1). 2.746 → 2.75; 1.743 → 1.74. In a multi-step calculation keep one extra digit in intermediate steps and round only at the end (reciprocal of 9.58 is 0.1044, not 0.104, otherwise 1/0.104 = 9.62 would not return 9.58). Exact numbers such as 2π or the speed of light 2.99792458 × 108 m s−1 may be rounded as needed (π = 3.14 or 3.142; c = 3 × 108).
Worked examples from the text
| Example | Working | Answer |
|---|---|---|
| 1.1 Cube side 7.203 m (4 s.f.): area and volume | 6(7.203)2 = 311.299254; (7.203)3 = 373.714754 | Area 311.3 m2, volume 373.7 m3 |
| 1.2 5.74 g in 1.2 cm3 | Mass 3 s.f., volume 2 s.f. so keep 2 | Density 4.8 g cm−3 |
1.3.3 Uncertainty in the results of arithmetic calculations
- Product of two measurements. l = 16.2 ± 0.1 cm = 16.2 cm ± 0.6% and b = 10.1 ± 0.1 cm = 10.1 cm ± 1%. Then l b = 163.62 cm2 ± 1.6% = 163.62 ± 2.6 cm2, quoted as 164 ± 3 cm2.
- Data combined to n significant figures stay valid to n figures, but subtraction can reduce them: 12.9 g − 7.06 g is 5.8 g, not 5.84 g (decimal-place rule).
- Relative error depends on the number itself, not only on n: 1.02 g ± 0.01 g has relative error 1%; 9.89 g ± 0.01 g has 0.1%.
1.4 Dimensions of physical quantities
The dimensions of a quantity are the powers to which the base quantities must be raised to represent it. The seven base quantities (the seven ‘dimensions of the physical world’) are written in square brackets: length [L], mass [M], time [T], electric current [A], thermodynamic temperature [K], luminous intensity [cd], amount of substance [mol]. Example: volume = length × breadth × height, so [V] = [L]3 = [M0 L3 T0]; force = mass × acceleration, so [F] = [M][L]/[T]2 = [M L T−2]. Only the nature of the quantity matters, not its magnitude: change in velocity, initial velocity, average velocity and speed all have dimensions [L T−1].
1.5 Dimensional formulae and dimensional equations
The expression showing which base quantities, and with what powers, make up a physical quantity is its dimensional formula (volume [M0 L3 T0], speed [M0 L T−1], acceleration [M0 L T−2], mass density [M L−3 T0]). An equation equating the quantity to its dimensional formula is a dimensional equation: [V] = [M0 L3 T0], [v] = [M0 L T−1], [F] = [M L T−2], [ρ] = [M L−3 T0].
| Physical quantity | Formula used | Dimensional formula | SI unit |
|---|---|---|---|
| Area | length × breadth | [L2] | m2 |
| Density | mass / volume | [M L−3] | kg m−3 |
| Velocity | displacement / time | [L T−1] | m s−1 |
| Acceleration | velocity / time | [L T−2] | m s−2 |
| Momentum | mass × velocity | [M L T−1] | kg m s−1 |
| Force | mass × acceleration | [M L T−2] | N |
| Work, energy | force × distance | [M L2 T−2] | J |
| Power | work / time | [M L2 T−3] | W |
| Pressure | force / area | [M L−1 T−2] | Pa |
| Frequency | 1 / time | [T−1] | Hz |
| Angle, refractive index, strain | ratio of like quantities | dimensionless | — |
1.6 Dimensional analysis and its applications
Only quantities with the same dimensions can be added or subtracted, and both sides of any correct equation must have the same dimensions. Units and dimensions are treated like algebraic symbols (identical ones cancel). Dimensional analysis is used to check consistency, to deduce relations (up to a dimensionless constant) and to convert units.
1.6.1 Checking dimensional consistency (principle of homogeneity)
- Terms added or subtracted must have identical dimensions; the arguments of trigonometric, logarithmic and exponential functions must be dimensionless; pure numbers and ratios of like quantities (angle, refractive index) have no dimensions.
- Test: x = x0 + v0 t + (1/2) a t2: [x] = [x0] = [L], [v0 t] = [L T−1][T] = [L], [(1/2) a t2] = [L T−2][T2] = [L]. All terms have dimension of length, so the equation is dimensionally correct.
- A dimensionally wrong equation must be wrong; a dimensionally correct one need not be correct (it is uncertain to the extent of dimensionless constants and functions).
| Example | Reasoning | Result |
|---|---|---|
| 1.3 Is (1/2) m v2 = m g h dimensionally correct? | LHS [M][L T−1]2 = [M L2 T−2]; RHS [M][L T−2][L] = [M L2 T−2] | Dimensionally correct (it is the equation of energy conservation for fall from rest) |
| 1.4 Which kinetic-energy formula can be ruled out? K = m2 v3, (1/2)mv2, ma, (3/16)mv2, (1/2)mv2 + ma | Dimensions: [M2 L3 T−3], [M L2 T−2], [M L T−2], [M L2 T−2], and a sum of unlike terms | Rule out (a), (c), (e); dimensions cannot choose between (b) and (d): the definition gives K = (1/2) m v2 |
1.6.2 Deducing relations among physical quantities
Example 1.5: time period of a simple pendulum. Assume T = k l^x g^y m^z. Dimensions: [L0 M0 T1] = [L]^x [L T−2]^y [M]^z = Lx+y T-2y M^z. Equate: x + y = 0, −2y = 1, z = 0 ⇒ x = 1/2, y = −1/2, z = 0, so T = k √(l/g). The mass does not appear. The dimensionless constant k cannot be found by this method (it is actually 2π, giving T = 2π√(l/g)).
Limitations of dimensional analysis: (i) cannot give dimensionless constants (1/2, 2π); (ii) cannot distinguish between quantities of the same dimensions (work and torque, energy and moment of force); (iii) fails for relations involving sums or trigonometric/exponential functions and when a quantity depends on more than three others in product form; (iv) tests only the form, not the exact correctness.
Ex 1.1 — Fill in the blanks: (a) The volume of a cube of side 1 cm is equal to ….. m3 (b) The surface area of a solid cylinder of radius 2.0 cm and height 10.0 cm is equal to …(mm)2 (c) A vehicle moving with a speed of 18 km h−1 covers ….m in 1 s (d) The relative density of lead is 11.3. Its density is ….g cm−3 or ….kg m−3.
Concept. Each blank needs a unit conversion together with the correct number of significant figures. The golden rule is to treat units like algebraic symbols: replace each unit by its equivalent in the required unit, raise the conversion factor to the same power as the unit, and then multiply. Conversion never changes the number of significant figures.
(a) Volume of a cube of side 1 cm in m3
- 1 cm = 10−2 m, so 1 cm3 = (10−2 m)3 = 10−6 m3 (the factor is cubed because volume has dimension [L3]).
- Volume of cube = (side)3 = (1 cm)3 = 1 cm3.
- Answer: 10−6 m3. (Check: 1 m3 = 106 cm3 = 103 litre.)
(b) Total surface area of a solid cylinder (r = 2.0 cm, h = 10.0 cm) in (mm)2
- For a solid cylinder the surface consists of curved surface 2πrh plus two circular ends 2πr2. Total = 2πr(r + h).
- r + h = 2.0 cm + 10.0 cm = 12.0 cm.
- Area = 2 × 3.14 × 2.0 cm × 12.0 cm = 150.8 cm2 ≈ 1.5 × 102 cm2 (two significant figures, because r = 2.0 cm has only two).
- 1 cm = 10 mm ⇒ 1 cm2 = 102 mm2. Area = 1.5 × 102 × 102 mm2.
- Answer: 1.5 × 104 (mm)2.
(c) Distance covered in 1 s at 18 km h−1
- 18 km h−1 = 18 × (1000 m) / (3600 s) = 18 × (5/18) m s−1 = 5.0 m s−1.
- Distance = speed × time = 5.0 m s−1 × 1 s.
- Answer: 5.0 m (shortcut: to convert km h−1 to m s−1 multiply by 5/18).
(d) Density of lead (relative density 11.3)
- Relative density = density of the substance / density of water at 4 °C. Density of water = 1 g cm−3 = 103 kg m−3.
- Density of lead = 11.3 × 1 g cm−3 = 11.3 g cm−3.
- In SI: 11.3 × 103 kg m−3 = 1.13 × 104 kg m−3 (1 g cm−3 = 10−3 kg / 10−6 m3 = 103 kg m−3).
| Part | Quantity | Working | Answer |
|---|---|---|---|
| (a) | Volume of cube | (10−2 m)3 | 10−6 m3 |
| (b) | Surface area | 2πr(r + h) = 150.8 cm2 = 1.5 × 102 cm2 | 1.5 × 104 mm2 |
| (c) | Distance in 1 s | 18 × 5/18 | 5.0 m |
| (d) | Density of lead | 11.3 × 1 g cm−3 | 11.3 g cm−3 = 1.13 × 104 kg m−3 |
Extra depth. Relative density (specific gravity) is a pure ratio and has no unit. The same numerical value gives density in g cm−3 directly, and in kg m−3 after multiplying by 1000. Always convert area by squaring and volume by cubing the length conversion factor: 1 cm2 = 102 mm2 = 10−4 m2; 1 cm3 = 103 mm3 = 10−6 m3. For (b) the answer must contain two significant figures because the least precise datum, r = 2.0 cm, has two.
Conclusion: (a) 10−6; (b) 1.5 × 104; (c) 5.0 m; (d) 11.3 g cm−3 and 1.13 × 104 kg m−3.
Ex 1.2 — Fill in the blanks by suitable conversion of units: (a) 1 kg m2 s−2 = ….g cm2 s−2 (b) 1 m = ….. ly (c) 3.0 m s−2 = …. km h−2 (d) G = 6.67 × 10−11 N m2 (kg)−2 = …. (cm)3 s−2 g−1.
Concept. Unit conversion by the factor-label method: write the quantity, multiply by conversion factors written so that the unwanted unit cancels, and carry the powers. Required constants: 1 kg = 103 g, 1 m = 102 cm, 1 km = 103 m, 1 h = 3600 s, and 1 light year (ly) = 9.46 × 1015 m.
| Part | Conversion | Working | Answer |
|---|---|---|---|
| (a) | kg m2 s−2 → g cm2 s−2 | 1 kg = 103 g; 1 m2 = (102 cm)2 = 104 cm2; s−2 unchanged. 1 kg m2 s−2 = 103 × 104 g cm2 s−2 | 107 g cm2 s−2 (1 joule = 107 erg) |
| (b) | m → light year | 1 ly = 9.46 × 1015 m ⇒ 1 m = 1/(9.46 × 1015) ly | 1.06 × 10−16 ly |
| (c) | m s−2 → km h−2 | 1 m = 10−3 km; 1 s = (1/3600) h so 1 s−2 = (3600)2 h−2 = 1.296 × 107 h−2. 3.0 × 10−3 × 1.296 × 107 | 3.9 × 104 km h−2 |
| (d) | N m2 kg−2 → cm3 s−2 g−1 | N = kg m s−2, so G = 6.67 × 10−11 m3 kg−1 s−2. 1 m3 = 106 cm3; 1 kg−1 = 10−3 g−1. 6.67 × 10−11 × 106 × 10−3 | 6.67 × 10−8 cm3 s−2 g−1 |
Step-by-step for (c) (the part most students get wrong)
- 3.0 m s−2 = 3.0 × (10−3 km) / (1/3600 h)2.
- (1/3600 h)2 = (1/3600)2 h2, so dividing by it multiplies by 36002 = 1.296 × 107.
- 3.0 × 10−3 × 1.296 × 107 = 3.888 × 104 ≈ 3.9 × 104 km h−2 (two significant figures).
Why (b) is a very small number: a light year is a unit of distance, the distance travelled by light in one year, so 1 ly = (3.00 × 108 m s−1)(3.156 × 107 s) = 9.46 × 1015 m. One metre is therefore a tiny fraction (10−16) of it.
Extra depth. In (d) the conversion needs a prior step of writing the newton in base units, N = kg m s−2. This is a standard idea: every derived unit must first be reduced to base units before converting. Check with dimensions: [G] = [M−1 L3 T−2]; converting the three base units gives factors (103)−1 (102)3 = 103, so 6.67 × 10−11 m3 kg−1 s−2 becomes 6.67 × 10−11 × 106/103 = 6.67 × 10−8 in cgs. Generally, if a quantity has dimensions [M^a L^b T^c], its numerical value in cgs is the SI value multiplied by (103)^a (102)^b.
Conclusion: (a) 107 g cm2 s−2; (b) 1.06 × 10−16 ly; (c) 3.9 × 104 km h−2; (d) 6.67 × 10−8 cm3 s−2 g−1.
Ex 1.3 — A calorie is a unit of heat (energy in transit) and it equals about 4.2 J where 1 J = 1 kg m2 s−2. Suppose we employ a system of units in which the unit of mass equals α kg, the unit of length equals β m, the unit of time is γ s. Show that a calorie has a magnitude 4.2 α−1 β−2 γ2 in terms of the new units.
Concept. The numerical value of a physical quantity is inversely proportional to the size of the unit: nu = constant, i.e. n1 u1 = n2 u2. If the new unit is larger, the number measuring the same quantity is smaller. Use the dimensional formula of energy [M L2 T−2] to relate the two systems.
- Energy has dimensional formula [M1 L2 T−2]. In the old (SI) system 1 calorie = 4.2 J = 4.2 kg m2 s−2, so n1 = 4.2 with units u1 = kg m2 s−2.
- In the new system the units are: mass M2 = α kg, length L2 = β m, time T2 = γ s. The new unit of energy is u2 = M2 L22 T2−2 = α β2 γ−2 (kg m2 s−2).
- Since the same energy is measured: n1 u1 = n2 u2, so n2 = n1 (u1/u2) = 4.2 × [1 / (α β2 γ−2)].
- Hence n2 = 4.2 α−1 β−2 γ2. Proved.
n2 = n1 [M1/M2]^a [L1/L2]^b [T1/T2]^c = 4.2 [1 kg/α kg]1 [1 m/β m]2 [1 s/γ s]−2 = 4.2 α−1 β−2 γ2
| Quantity | Old value | New unit | New magnitude |
|---|---|---|---|
| Mass unit | 1 kg | α kg | α−1 per new unit of mass |
| Length unit | 1 m | β m | β−1 |
| Time unit | 1 s | γ s | γ−1 (so T−2 gives γ2) |
| Energy (calorie) | 4.2 (kg m2 s−2) | α β2 γ−2 kg m2 s−2 | 4.2 α−1 β−2 γ2 |
Extra depth. Example 1: if the new unit of mass is a tonne (α = 103) and β = γ = 1, the calorie becomes 4.2 × 10−3 new units, a smaller number because the new mass unit is larger. If the new system is CGS-like (α = 10−3, β = 10−2, γ = 1), then 4.2 α−1 β−2 = 4.2 × 103 × 104 = 4.2 × 107, which is the calorie in erg (1 J = 107 erg). This general scaling is used whenever systems of units are changed.
Conclusion: Using n1u1 = n2u2 and the dimensional formula [M L2 T−2], a calorie = 4.2 α−1 β−2 γ2 in the new units.
Ex 1.4 — Explain this statement clearly: “To call a dimensional quantity ‘large’ or ‘small’ is meaningless without specifying a standard for comparison”. In view of this, reframe the following statements wherever necessary: (a) atoms are very small objects (b) a jet plane moves with great speed (c) the mass of Jupiter is very large (d) the air inside this room contains a large number of molecules (e) a proton is much more massive than an electron (f) the speed of sound is much smaller than the speed of light.
Concept. A dimensional quantity is one that has a unit (length, speed, mass …). Its numerical value depends on the unit chosen: the same distance is 1 km, 1000 m or 105 cm, and whether the number is ‘big’ is arbitrary. Words like ‘large’ and ‘small’ are therefore meaningful only when a standard (a quantity of the same kind) is specified and the ratio of the two is stated; a ratio of like quantities is a pure number that does not depend on units.
Example of the idea. Is 1 mm large or small? Compared with the size of an atom (10−10 m) it is 107 times larger; compared with the size of the Earth (107 m) it is 10−10 times smaller. The statement ‘1 mm is small’ is incomplete without the comparison.
| Statement | Meaningful as it stands? | Reframed statement with a standard of comparison |
|---|---|---|
| (a) atoms are very small objects | No | The size of an atom (about 10−10 m) is very small compared with the size of everyday objects such as a ball (about 10−1 m): atoms are about 109 times smaller. |
| (b) a jet plane moves with great speed | No | The speed of a jet plane (about 300 m s−1, i.e. about 103 km h−1) is much greater than the speed of a bus or a car (about 20–30 m s−1); it is, however, much smaller than the speed of light (3 × 108 m s−1). |
| (c) the mass of Jupiter is very large | No | The mass of Jupiter (1.9 × 1027 kg) is very large compared with that of the Earth (6.0 × 1024 kg), about 318 times; but it is small compared with the mass of the Sun (2.0 × 1030 kg). |
| (d) the air inside this room contains a large number of molecules | No | The number of molecules in the air of this room (about 1027 for a room of about 40 m3) is large compared with the number of grains of sand in a bucket, or people living on the Earth (about 1010). |
| (e) a proton is much more massive than an electron | Yes | A ratio of masses (mp/me ≈ 1836) is already stated: the standard (electron mass) is given, so the statement needs no change. |
| (f) the speed of sound is much smaller than the speed of light | Yes | Again a ratio of like quantities (about 330 m s−1 : 3 × 108 m s−1, i.e. about 10−6) is implied; the statement is complete. |
Check with numbers. Number of molecules in 40 m3 of air at STP = (40 m3 / 22.4 × 10−3 m3 per mole) × 6.02 × 1023 = 1.8 × 103 mol × 6.02 × 1023 ≈ 1 × 1027, so the statement in (d) is valid with the standard ‘compared with the number of grains of sand in a bucket’.
Extra depth. In scientific statements, replace adjectives by ratios or orders of magnitude. A dimensionless number such as mp/me = 1836, or the Mach number v/vsound, is independent of the unit system and is therefore unambiguous. This is why physicists compare, for example, the strength of forces by dimensionless ratios (the gravitational force between two protons is about 10−36 times the electrostatic force) rather than by saying a force is ‘weak’ or ‘strong’. In SI the ‘order of magnitude’ (Section 1.3) gives the quick comparison: the Earth’s diameter is 17 orders of magnitude larger than that of a hydrogen atom.
Conclusion: A dimensional quantity can be called large or small only relative to a specified standard of the same kind; statements (a) to (d) need a standard of comparison, whereas (e) and (f) already contain one.
Ex 1.5 — A new unit of length is chosen such that the speed of light in vacuum is unity. What is the distance between the Sun and the Earth in terms of the new unit if light takes 8 min and 20 s to cover this distance?
Concept. When a unit is defined so that a certain physical constant has the numerical value 1, all other quantities are measured in terms of it. Here the new unit of length is the distance light travels in vacuum in one unit of time (one second), because speed = 1 new length unit per second.
- Given: speed of light c = 1 (new length unit) per second, i.e. 1 new unit = c × 1 s = 3 × 108 m (the unit is the ‘light-second’).
- Time taken by light from the Sun to reach the Earth: t = 8 min 20 s = 8 × 60 s + 20 s = 480 s + 20 s = 500 s.
- Distance = speed × time = (1 new unit per second) × (500 s) = 500 new units.
- Distance between Sun and Earth = 500 new units.
| Quantity | Value in SI | Value in the new unit |
|---|---|---|
| Speed of light | 3 × 108 m s−1 | 1 unit s−1 |
| Time of travel of sunlight | 500 s | 500 s |
| Distance Sun–Earth | 1.5 × 1011 m (= 3 × 108 × 500) | 500 units (1 unit = 3 × 108 m) |
Cross-check in SI: d = c t = 3 × 108 m s−1 × 500 s = 1.5 × 1011 m, the standard value of one astronomical unit. Dividing by the new unit (3 × 108 m) gives 1.5 × 1011/3 × 108 = 500. The distance is thus 500 light-seconds.
Extra depth. This idea underlies natural units used in relativity and particle physics, where c = 1 and distances are quoted in light-seconds, light-minutes or light-years (1 ly = 9.46 × 1015 m). In the 2018 SI the metre itself is defined by fixing the numerical value of the speed of light c = 299 792 458 m s−1 and defining the second through the caesium frequency; thus the accepted unit of length is already tied to c. Also note that this problem does not require the actual value of c: whatever the unit, if c = 1 then distance = time of light travel, so the answer is simply 500.
More to know — units based on constants. Setting c = 1 is routine in relativity: time and distance then have the same unit (one second of time corresponds to one light-second of distance, 3 × 108 m), and the Sun–Earth distance of 1 astronomical unit is 500 light-seconds. Other familiar astronomical units: 1 light year = 9.46 × 1015 m; 1 parsec = 3.08 × 1016 m (about 3.26 ly); the Moon is only 1.3 light-seconds away. The delay of about 8 min 20 s is also the time lag with which we see the Sun: we always see the Sun as it was 500 s ago.
Conclusion: The Sun–Earth distance is 500 new units (500 light-seconds = 1.5 × 1011 m).
Ex 1.6 — Which of the following is the most precise device for measuring length: (a) a vernier callipers with 20 divisions on the sliding scale (b) a screw gauge of pitch 1 mm and 100 divisions on the circular scale (c) an optical instrument that can measure length to within a wavelength of light?
Concept. The precision of a measuring device is set by its least count, the smallest length it can measure reliably. The device with the smallest least count is the most precise.
| Device | Formula for least count | Least count | In metres |
|---|---|---|---|
| (a) Vernier callipers, 20 divisions on vernier (1 main-scale division = 1 mm) | 1 MSD / number of vernier divisions = 1 mm / 20 | 0.05 mm | 5 × 10−5 m |
| (b) Screw gauge, pitch 1 mm, 100 circular divisions | Pitch / number of circular divisions = 1 mm / 100 | 0.01 mm | 1 × 10−5 m |
| (c) Optical instrument, resolution about one wavelength of visible light (5 × 10−7 m) | Wavelength of light | about 0.0005 mm | 5 × 10−7 m |
- Least count of (a): 0.05 mm = 5 × 10−5 m.
- Least count of (b): 0.01 mm = 10−5 m, five times finer than (a).
- Least count of (c): about 5 × 10−7 m (a wavelength of light), twenty times finer than (b) and a hundred times finer than (a).
- Hence (c) the optical instrument is the most precise.
Ranking: optical instrument (5 × 10−7 m) > screw gauge (10−5 m) > vernier callipers (5 × 10−5 m). A device cannot resolve distances smaller than the wavelength of the light used; that is why wavelength of light is the practical limit for optical measurement of length.
Extra depth. Observe that more precision is not the same as more accuracy: precision is the resolution of the instrument (how many digits can be read), accuracy is how close the reading is to the true value. A badly calibrated screw gauge with a zero error is precise but inaccurate. Instruments with still finer resolution (electron microscopes, scanning tunnelling microscopes) use radiation of shorter wavelength to measure atomic sizes of 10−10 m, which a visible-light optical instrument cannot do.
Conclusion: The most precise device is (c), the optical instrument, since its least count (about 5 × 10−7 m) is smaller than that of the screw gauge (10−5 m) and the vernier callipers (5 × 10−5 m).
Ex 1.7 — A student measures the thickness of a human hair by looking at it through a microscope of magnification 100. He makes 20 observations and finds that the average width of the hair in the field of view of the microscope is 3.5 mm. What is the estimate on the thickness of hair?
Concept. A microscope of linear magnification m produces an image whose width is m times the real width: m = (size of image)/(size of object). So the real thickness = (width seen)/(magnification). The mean of 20 observations is used to reduce random error.
- Magnification m = 100; mean observed (image) width = 3.5 mm.
- Real thickness = observed width / magnification = 3.5 mm / 100.
- Thickness = 0.035 mm = 3.5 × 10−2 mm = 3.5 × 10−5 m.
- The thickness of the hair is about 0.035 mm (3.5 × 10−5 m).
| Quantity | Value |
|---|---|
| Magnification of microscope | 100 |
| Average width seen in the field of view | 3.5 mm |
| Number of observations | 20 (random errors reduced by averaging) |
| Actual thickness = 3.5 mm / 100 | 0.035 mm = 35 μm |
| Significant figures | 2 (limited by 3.5 mm) |
Meaning of the result. 35 μm is of the order of 10−5 m, typical for human hair (from about 20 to 100 μm); the hair is thinner than the least count of a vernier callipers (0.05 mm) and similar to that of a screw gauge (0.01 mm), so a microscope is the proper instrument.
Extra depth. Twenty observations are taken because the width varies from place to place along the hair and each reading carries random error: the mean of many readings is a more reliable estimate and its random error decreases as 1/√N. The result has only two significant figures because 3.5 mm has two. The microscope magnification (100) is an exact number and does not limit the significant figures.
More to know — magnification and measuring small sizes. The image seen in a microscope is larger than the object by the magnification: object size = image size/magnification, so a hair that appears 3.5 mm wide through a 100× microscope is really 0.035 mm = 35 μm wide. Typical scales for comparison: human hair 20–100 μm; red blood cell about 7 μm; bacterium about 1 μm; wavelength of visible light 0.4–0.7 μm; virus about 0.1 μm; hydrogen atom about 10−10 m = 10−4 μm. A vernier callipers (0.05 mm = 50 μm) cannot measure the hair directly because its least count is of the same order as the quantity measured, so the relative error would be about 100%.
Conclusion: The thickness of the hair is 3.5 mm / 100 = 0.035 mm (3.5 × 10−5 m).
Ex 1.8 — Answer the following: (a) You are given a thread and a metre scale. How will you estimate the diameter of the thread? (b) A screw gauge has a pitch of 1.0 mm and 200 divisions on the circular scale. Do you think it is possible to increase the accuracy of the screw gauge arbitrarily by increasing the number of divisions on the circular scale? (c) The mean diameter of a thin brass rod is to be measured by vernier callipers. Why is a set of 100 measurements of the diameter expected to yield a more reliable estimate than a set of 5 measurements only?
Concept. These three parts test practical measurement ideas: magnifying a small quantity by repetition (a), the difference between least count and true accuracy (b) and the reduction of random error by averaging (c).
(a) Diameter of a thread with a metre scale
- Wind the thread closely on a uniform pencil (or glass rod) so that the turns touch each other, with no overlap and no gap; count the number of turns N, say N = 20.
- Using the metre scale measure the length L of the wound portion from the first to the last turn.
- Diameter of the thread d = L / N. If L = 1.60 cm for N = 20 turns, d = 0.080 cm = 0.80 mm.
- Repeat several times with different N and take the mean value to reduce error.
This method works because the metre scale cannot measure a very small length directly (its least count is 1 mm), but it can measure a large multiple N d accurately; the uncertainty 0.5 mm in L is divided by N, so the uncertainty in d becomes 0.5/20 = 0.025 mm.
(b) Can the accuracy of a screw gauge be increased arbitrarily by increasing the divisions?
No. The least count of the screw gauge is pitch / number of divisions = 1.0 mm / 200 = 0.005 mm. Increasing the divisions makes the least count numerically smaller but not the accuracy without limit, because accuracy is limited by other factors:
- Mechanical imperfections of the screw: the actual pitch of the thread is not uniform, and there is backlash (lost motion) in the thread.
- The faces of the screw and the stud are never perfectly flat or parallel, and the object may be slightly compressed, depending on the pressure applied (the ratchet reduces but does not remove this).
- As the divisions become closer it becomes physically impossible to see and read them separately (they cannot be closer than the width of a visible line), and human judgement of alignment introduces error.
- Temperature changes expand the screw and the object. So there is a practical limit beyond which more divisions give no gain in true accuracy.
(c) 100 measurements versus 5 measurements of the diameter
- The reading of the vernier callipers scatters about the true value because of random errors (slightly different positions along the rod, slightly different pressure, judgement of the coinciding division). Random errors are as likely to be positive as negative.
- When many readings are averaged, positive and negative errors tend to cancel, so the mean is closer to the true value.
- The uncertainty of the mean decreases as 1/√N. For N = 100 the random error of the mean is smaller than for N = 5 by √(100/5) = √20 ≈ 4.5 times.
- So a set of 100 measurements gives a more reliable estimate (it reduces random errors, not systematic errors such as a zero error, which must be corrected separately).
Extra depth. The same idea (averaging to beat random noise) is used in every experiment, from the 20 observations of Ex 1.7 to the thousands of events accumulated at a particle collider. Systematic errors (zero error, wrong calibration) are not reduced by taking more readings; they are removed only by correcting the instrument. A screw gauge of 200 divisions is therefore not necessarily better than one of 100 if its screw is of poor quality.
Conclusion: (a) Wind N close turns on a pencil and divide the length by N; (b) no, accuracy is limited by screw defects, backlash and reading difficulty; (c) averaging 100 readings cancels random errors much better than averaging 5.
Ex 1.9 — The photograph of a house occupies an area of 1.75 cm2 on a 35 mm slide. The slide is projected on to a screen, and the area of the house on the screen is 1.55 m2. What is the linear magnification of the projector-screen arrangement.
Concept. Linear magnification m is the ratio of a length in the image to the corresponding length in the object: m = limage/lobject. Areas scale as the square of lengths, so the ratio of areas equals m2.
- Area of the house on the slide A1 = 1.75 cm2 = 1.75 × 10−4 m2 (1 cm2 = 10−4 m2).
- Area of the house on the screen A2 = 1.55 m2.
- Area magnification = A2/A1 = 1.55 m2 / (1.75 × 10−4 m2) = 8.857 × 103.
- Since A ∝ l2: m2 = 8.857 × 103, so m = √(8.857 × 103) = 94.1.
- Linear magnification m ≈ 94. (Three significant figures in data, so 94.1; the NCERT answer is quoted as 94.)
| Step | Quantity | Value |
|---|---|---|
| 1 | Area on slide | 1.75 cm2 = 1.75 × 10−4 m2 |
| 2 | Area on screen | 1.55 m2 |
| 3 | Ratio of areas | 8.86 × 103 (= m2) |
| 4 | Linear magnification | √(8.86 × 103) = 94 |
Why the square root? If every length is magnified by m, then both the width and the height of the picture become m times larger, so the area becomes m × m = m2 times larger. The 35 mm in the question is the width of the slide film and is not needed for the calculation (it is a distractor).
Extra depth. Common error: quoting 8.86 × 103 as the ‘magnification’. That is the area magnification. Linear magnification is the square root: lengths on the screen are 94 times the lengths on the slide, e.g. a house 1 cm tall on the slide appears 94 cm tall on the screen. This is typical of Class XI conversions of ratio of areas, volumes (m3) and lengths (m); in similar problems on volumes use the cube root.
More to know — scaling laws. If lengths scale by m, then areas scale by m2 and volumes by m3. For the projector: 1 cm on the slide becomes 94 cm on the screen, area 1.75 cm2 becomes 942 × 1.75 cm2 = 1.55 × 104 cm2 = 1.55 m2 ✓. These ideas return in optics (lateral magnification of lenses and mirrors, Class XII) and in similar-figure problems of biology and engineering: a model one-tenth the size has one-hundredth the area and one-thousandth the volume.
Conclusion: The linear magnification of the projector-screen arrangement is about 94.
Ex 1.10 — State the number of significant figures in the following: (a) 0.007 m2 (b) 2.64 × 1024 kg (c) 0.2370 g cm−3 (d) 6.320 J (e) 6.032 N m−2 (f) 0.0006032 m2
Concept. Count digits from the first non-zero digit to the last digit, including trailing zeros if there is a decimal point. Leading zeros (before the first non-zero digit) are never significant; the power of ten in scientific notation never counts.
| Part | Number | Reasoning | Significant figures |
|---|---|---|---|
| (a) | 0.007 m2 | Leading zeros are not significant; only the digit 7 counts | 1 |
| (b) | 2.64 × 1024 kg | Digits 2, 6, 4 of the base number; 1024 is irrelevant | 3 |
| (c) | 0.2370 g cm−3 | Leading 0 not significant; 2, 3, 7 and the trailing 0 (after a decimal point) are significant | 4 |
| (d) | 6.320 J | 6, 3, 2 and the trailing zero after the decimal point | 4 |
| (e) | 6.032 N m−2 | The zero between 6 and 3 is between non-zero digits: all four digits count | 4 |
| (f) | 0.0006032 m2 | Leading zeros (0.000) do not count; 6, 0, 3, 2 count (the 0 is between non-zero digits) | 4 |
Rules used (Section 1.3)
- Non-zero digits are always significant.
- Zeros between non-zero digits are significant.
- Leading zeros (to the left of the first non-zero digit) are not significant.
- Trailing zeros after the decimal point are significant.
- The power of ten in scientific notation is not counted.
Scientific-notation check: (a) 7 × 10−3 (1 digit); (c) 2.370 × 10−1 (4 digits); (f) 6.032 × 10−4 (4 digits). Writing numbers in scientific notation shows at once how many significant figures there are.
Extra depth. The number of significant figures does not change if the unit is changed: 0.2370 g cm−3 = 237.0 kg m−3 (still four). Be careful with a number like 2300 (no decimal point): the trailing zeros are ambiguous and are taken as not significant (two figures); writing 2.300 × 103 removes the ambiguity (four figures). The number of significant figures indicates the precision: 0.007 m2 is uncertain by 1 part in 7 (about 14%), while 0.0006032 m2 is uncertain by 1 part in 6000.
More to know — why significant figures matter. A reading of 0.007 m2 (one significant figure) implies a possible error of 0.0005 m2 (about 7%), while 0.0006032 m2 (four significant figures) implies an error of about 0.00000005 m2 (about 0.01%). Reporting more figures than the instrument justifies would claim a precision that does not exist. Typical exam trap: 6.320 J must keep its trailing zero because it records that the hundredths–thousandths place was measured, whereas 6.32 J would claim less precision.
Conclusion: (a) 1; (b) 3; (c) 4; (d) 4; (e) 4; (f) 4.
Ex 1.11 — The length, breadth and thickness of a rectangular sheet of metal are 4.234 m, 1.005 m, and 2.01 cm respectively. Give the area and volume of the sheet to correct significant figures.
Concept. Convert all dimensions to the same unit (metre), then compute and round to the least number of significant figures among the factors. The thickness 2.01 cm has only three significant figures, so the volume must be reported to three; the length and breadth have four.
- l = 4.234 m (4 s.f.), b = 1.005 m (4 s.f.), t = 2.01 cm = 0.0201 m = 2.01 × 10−2 m (3 s.f.).
- Area of the sheet. A sheet has two faces of area l b and four edges: total surface area = 2(lb + bt + tl). lb = 4.234 × 1.005 = 4.2552; bt = 1.005 × 0.0201 = 0.0202; tl = 0.0201 × 4.234 = 0.0851.
- Sum = 4.2552 + 0.0202 + 0.0851 = 4.3605 m2; area = 2 × 4.3605 = 8.721 m2. Since the thickness has three significant figures the area is 8.72 m2.
- Volume. V = l b t = 4.234 m × 1.005 m × 2.01 × 10−2 m = 8.5529 × 10−2 m3. Rounding to three significant figures gives 8.55 × 10−2 m3.
| Quantity | Calculation | Raw result | Reported (3 s.f.) |
|---|---|---|---|
| Area of one face l × b | 4.234 × 1.005 | 4.2552 m2 | 4.255 m2 (4 s.f., both factors have four) |
| Total surface area 2(lb + bt + tl) | 2(4.2552 + 0.0202 + 0.0851) | 8.721 m2 | 8.72 m2 |
| Volume l b t | 4.234 × 1.005 × 0.0201 | 0.085529 m3 | 8.55 × 10−2 m3 |
Note on the meaning of ‘area’. For a sheet, ‘area’ means the total surface area (both faces and the edges), the standard NCERT answer being 8.72 m2. If only the area of one face were wanted, it would be 4.255 m2. The two edge strips together contribute only 0.2% of the area, but they are included when the sheet is taken as a cuboid.
Extra depth. The rule applied is that in a product the result has as many significant figures as the factor with the fewest significant figures: here 2.01 cm (three). In the addition inside the bracket the rule is by decimal places, but the smaller terms (0.0202, 0.0851) have more decimal places than needed, so the final area is governed by the least precise factor, the thickness, giving 8.72. Always keep one extra digit during the calculation (4.2552, not 4.26) and round only at the end.
Conclusion: The sheet has a surface area of 8.72 m2 and a volume of 8.55 × 10−2 m3.
Ex 1.12 — The mass of a box measured by a grocer’s balance is 2.30 kg. Two gold pieces of masses 20.15 g and 20.17 g are added to the box. What is (a) the total mass of the box, (b) the difference in the masses of the pieces to correct significant figures?
Concept. For addition and subtraction the rule is in terms of decimal places, not significant figures: the result must have as many decimal places as the number with the fewest decimal places, after all the quantities are expressed in the same unit.
(a) Total mass of the box
- Convert the gold masses to kilograms: 20.15 g = 0.02015 kg and 20.17 g = 0.02017 kg.
- Total = 2.30 kg + 0.02015 kg + 0.02017 kg = 2.34032 kg.
- The balance reads 2.30 kg, with only two decimal places (hundredths of a kilogram), so the answer must have two decimal places.
- Rounding 2.34032 to two decimal places: 2.34 kg.
(b) Difference in the masses of the gold pieces
- Difference = 20.17 g − 20.15 g = 0.02 g.
- Both numbers have two decimal places (the measurement precision is 0.01 g), so the answer keeps two decimal places: 0.02 g (one significant figure).
| Part | Operation | Raw answer | Reported |
|---|---|---|---|
| (a) | 2.30 kg + 0.02015 kg + 0.02017 kg | 2.34032 kg | 2.34 kg (2 decimal places) |
| (b) | 20.17 g − 20.15 g | 0.02 g | 0.02 g (2 decimal places) |
Meaning. The grocer’s balance cannot detect the gold pieces separately: adding 40.32 g to a box of 2.30 kg changes the reading from 2.30 kg to only 2.34 kg. The difference of 0.02 g between the two pieces is much smaller than the balance’s precision (10 g) and so is only meaningful if the gold pieces were weighed on a more sensitive balance, as the 0.01 g precision of their masses shows.
Extra depth. In subtraction, significant figures can be lost: 20.17 g and 20.15 g each have four significant figures, but their difference 0.02 g has only one. This is why subtracting two nearly equal numbers is bad practice experimentally: the relative error of the difference becomes large (here ±0.01 g in 0.02 g is 50%). The grocer’s-balance total, on the other hand, is limited by the least precise item, the 2.30 kg reading.
More to know — absolute and relative error. The grocer’s balance has an absolute uncertainty of ±0.01 kg (10 g) in 2.30 kg (relative error 0.4%), so extra 40 g changes the reading by about four units in the last place only. The gold pieces, with ±0.01 g in 20.15 g, have a relative error of 0.05%. Their difference, 0.02 g, has an absolute uncertainty of up to ±0.02 g (errors add in subtraction), i.e. up to 100% relative error: a clear illustration of why differences of nearly equal numbers lose significance.
Conclusion: (a) The total mass is 2.34 kg; (b) the difference in the masses of the gold pieces is 0.02 g.
Ex 1.13 — A famous relation in physics relates ‘moving mass’ m to the ‘rest mass’ mo of a particle in terms of its speed v and the speed of light, c. (This relation first arose as a consequence of special relativity due to Albert Einstein). A boy recalls the relation almost correctly but forgets where to put the constant c. He writes: m = mo / (1 − v2)1/2. Guess where to put the missing c.
Concept. Use the principle of homogeneity of dimensions: only quantities with the same dimensions can be added or subtracted, and the argument of a power such as (1 − x)1/2 must be dimensionless if ‘1’ (a pure number) appears in it.
- In the expression (1 − v2)1/2 the number 1 is dimensionless, so v2 must also be dimensionless for the subtraction 1 − v2 to be meaningful.
- But v2 has dimensions [L2 T−2] (it is a speed squared). To make it dimensionless divide by another quantity with the same dimensions: the only speed in the problem is c, with [c2] = [L2 T−2].
- Hence the correct term is v2/c2, which is dimensionless.
- The relation is therefore m = mo / (1 − v2/c2)1/2.
| Expression | Dimensions of v2 term | Consistent? |
|---|---|---|
| (1 − v2) | [L2 T−2] subtracted from a pure number | No |
| (1 − v2/c2) | [L2 T−2]/[L2 T−2] = dimensionless | Yes |
| (1 − v/c) | dimensionless, but not the correct (relativistic) form | Dimensionally yes, but dimensional analysis cannot tell it from the right one |
Physical check. For v ≪ c, v2/c2 ≈ 0 and m ≈ mo: the mass is the rest mass, as in everyday motion. As v → c the denominator tends to zero and m grows without limit: no massive particle can reach the speed of light. At v = 0.6c, m = mo/√(1 − 0.36) = mo/0.8 = 1.25 mo.
Extra depth. Dimensional analysis shows where c must occur but cannot fix dimensionless numbers or functions: it cannot tell (1 − v2/c2)1/2 from, say, (1 − v2/c2)1/2 multiplied by a pure number, or from a function of v/c with the same dimensions. The factor v2 and the exponent 1/2 are taken from the boy’s memory of Einstein’s relation; dimensional analysis only certifies that the corrected formula is consistent. This is exactly the limitation stated in Section 1.6: a dimensionally correct equation need not be correct.
Conclusion: The missing c belongs under v2: m = mo / (1 − v2/c2)1/2.
Ex 1.14 — The unit of length convenient on the atomic scale is known as an angstrom and is denoted by Å: 1 Å = 10−10 m. The size of a hydrogen atom is about 0.5 Å. What is the total atomic volume in m3 of a mole of hydrogen atoms?
Concept. The atom is treated as a sphere whose volume is (4/3)πr3, and one mole contains Avogadro’s number NA = 6.022 × 1023 atoms. The total atomic volume of a mole is NA times the volume of one atom. The ‘size’ 0.5 Å is taken as the radius of the hydrogen atom, as in the NCERT solution.
- Radius r = 0.5 Å = 0.5 × 10−10 m = 5 × 10−11 m.
- Volume of one hydrogen atom V1 = (4/3)πr3 = (4/3) × 3.14 × (5 × 10−11 m)3 = (4/3) × 3.14 × 1.25 × 10−31 m3 = 5.2 × 10−31 m3.
- Total atomic volume of one mole = NA V1 = 6.022 × 1023 × 5.2 × 10−31 m3 = 3.2 × 10−7 m3.
- The size is given to one significant figure (0.5 Å), so the answer is about 3 × 10−7 m3.
| Quantity | Value |
|---|---|
| Radius of H atom | 0.5 Å = 5 × 10−11 m |
| Volume of one atom (4/3)πr3 | 5.2 × 10−31 m3 |
| Number of atoms in one mole | 6.022 × 1023 |
| Total atomic volume | 3 × 10−7 m3 (= 0.3 cm3) |
Sense of scale. 3 × 10−7 m3 is only 0.3 cm3 (the size of a pea) for a whole mole (6.0 × 1023 atoms, mass about 1 g). The space occupied by the matter of atoms is tiny; the volume of a mole of hydrogen gas under normal conditions is 22.4 litres (Ex 1.15), much larger. A solid or liquid, in which atoms are packed closely, has a molar volume of the order of 10 cm3 — still about a factor of 30 more than the sum of the atomic volumes because atoms are not tightly packed spheres.
Extra depth. If the 0.5 Å had been the diameter, the radius would be 0.25 Å and the volume eight times smaller. The question states ‘size’ and NCERT takes it as the radius (using standard Bohr radius of hydrogen 0.53 Å, which supports the radius interpretation). The calculation relies on the order of magnitude: 10−31 m3 for one atom, 10−7 m3 for a mole.
Conclusion: The total atomic volume of a mole of hydrogen atoms is about 3 × 10−7 m3.
Ex 1.15 — One mole of an ideal gas at standard temperature and pressure occupies 22.4 L (molar volume). What is the ratio of molar volume to the atomic volume of a mole of hydrogen? (Take the size of hydrogen molecule to be about 1 Å). Why is this ratio so large?
Concept. The molar volume of an ideal gas at STP is the volume occupied by the container space for 6.022 × 1023 molecules; the atomic volume is the volume of the molecules themselves. Their ratio tells us how much of the gas is actually matter and how much is empty space.
- Molar volume Vm = 22.4 L = 22.4 × 10−3 m3 = 2.24 × 10−2 m3.
- Atomic volume of a mole of hydrogen (Ex 1.14, size 1 Å taken as for the atom, radius 0.5 Å) Va = 3 × 10−7 m3.
- Ratio Vm / Va = 2.24 × 10−2 m3 / 3 × 10−7 m3 = 7.5 × 104 (with the more precise Va = 3.15 × 10−7 m3, 7.1 × 104).
- The ratio is about 7 × 104, i.e. of the order of 105.
| Quantity | Value |
|---|---|
| Molar volume of an ideal gas at STP | 22.4 L = 2.24 × 10−2 m3 |
| Atomic volume of a mole of hydrogen | 3 × 10−7 m3 |
| Ratio | ≈ 7 × 104 ≈ 105 |
| Volume per molecule in the gas = 22.4 × 10−3 / 6.02 × 1023 | 3.7 × 10−26 m3 |
| Mean separation (cube root) | 3.3 × 10−9 m = 33 Å (about 30 times the molecular size) |
Why is the ratio so large?
- In a gas the molecules are very far apart compared with their own size: the average separation at STP is about 3.3 nm = 33 Å, roughly 30 times the molecular diameter (1 Å).
- The molecules actually occupy only about 1 part in 105 of the volume available; the rest is empty space. Since volume goes as (length)3, a separation of 30 diameters gives a volume ratio of about 303 ≈ 3 × 104, of the order observed.
- The intermolecular forces are weak at such distances, so molecules move almost independently; this is why gases are compressible and why an ideal gas can treat molecules as point particles.
- In solids and liquids the molecules are in contact (separation about one diameter), so the corresponding ratio is only of order 1–10.
Check using the volume per molecule. Vm/NA = 2.24 × 10−2 m3 / 6.02 × 1023 = 3.7 × 10−26 m3 per molecule, a cube of side (3.7 × 10−26)1/3 = 3.3 × 10−9 m. Dividing by the molecular diameter 10−10 m gives about 33. Cubing gives 3.6 × 104, consistent in order of magnitude with the ratio found above (the extra factor 2 arises from the sphere factor 4π/3 × (1/2)3 = 0.52 for the volume of the molecule).
Extra depth. The empty-space picture explains why gases can be compressed to the liquid state, why they diffuse and mix quickly, and why the ideal gas law (Chapter 12) neglects molecular volume. Compare the ratio for liquid water: 18 cm3 per mole against the atomic volume of about 10 cm3 (a factor of about 2): in liquids and solids the molecules are almost touching. The huge gas ratio of about 105 is the order-of-magnitude result NCERT expects.
Conclusion: The ratio of molar volume to atomic volume is about 105 (7 × 104) because the gas molecules are very far apart compared with their size, so most of the volume is empty space.
Ex 1.16 — Explain this common observation clearly: If you look out of the window of a fast moving train, the nearby trees, houses etc. seem to move rapidly in a direction opposite to the train’s motion, but the distant objects (hill tops, the Moon, the stars etc.) seem to be stationary. (In fact, since you are aware that you are moving, these distant objects seem to move with you).
Concept. The effect is called parallax: the apparent shift in the position of an object against a distant background when the observer changes position. What the eye notices is the angular velocity of the line of sight to the object, not its linear velocity, and this depends strongly on the distance of the object.
- Let the train (observer) move with speed v. In a short time t it moves a distance s = v t along the track, from O1 to O2.
- For an object at perpendicular distance d from the track, the line of sight turns through an angle θ (in radian) ≈ s/d = v t/d. The angular velocity of the line of sight is ω = θ/t = v/d.
- Nearby trees and houses have small d, so ω = v/d is large: the line of sight turns quickly and the object sweeps backwards across your field of view. The sense is opposite to the train’s motion because the observer moves forward relative to the object.
- Distant objects (hill tops, the Moon, stars) have very large d, so ω = v/d is almost zero; their direction in the sky hardly changes during the observation, so they appear stationary (or, since you know you are moving, seem to move along with you).
| Object | Typical distance d | ω = v/d for v = 30 m s−1 | Appearance |
|---|---|---|---|
| Tree beside the track | 20 m | 1.5 rad s−1 (about 86° per second) | Rushes backwards |
| Hill top | 5 km | 6 × 10−3 rad s−1 (0.34° per second) | Moves slowly |
| Moon | 3.8 × 108 m | 8 × 10−8 rad s−1 | Appears fixed (follows you) |
| Star (nearest, about 4 light years) | 4 × 1016 m | ≈ 10−15 rad s−1 | Absolutely fixed |
Application. The same principle is used to measure the distance of nearby stars (annual parallax) and in range-finding: from the angular shift θ for a known baseline b the distance is d = b/θ. Our two eyes use binocular parallax for depth perception.
Extra depth. Notice that the linear velocity relative to the train is the same for all objects (all appear to move with speed v relative to the train in the train frame); the difference lies in the angle turned through per second, which is what the eye senses. This is why in a flying aeroplane, ground objects directly below seem to rush past while distant clouds drift slowly. Parallax is also the reason that the stars show no apparent motion over a human lifetime even though the Earth moves at 30 km s−1 around the Sun.
Conclusion: Because the angle turned through by the line of sight in a given time is large for near objects (θ ≈ vt/d) and nearly zero for distant objects, near objects seem to move rapidly backwards and distant objects seem stationary (parallax).
Ex 1.17 — The Sun is a hot plasma (ionized matter) with its inner core at a temperature exceeding 107 K, and its outer surface at a temperature of about 6000 K. At these high temperatures, no substance remains in a solid or liquid phase. In what range do you expect the mass density of the Sun to be, in the range of densities of solids and liquids or gases? Check if your guess is correct from the following data: mass of the Sun = 2.0 × 1030 kg, radius of the Sun = 7.0 × 108 m.
Concept. At such high temperatures one might guess that the Sun’s matter is a gas of very low density. The data allow us to test this guess by computing the mean density ρ = mass / volume, treating the Sun as a sphere of volume (4/3)πR3.
- Volume of the Sun V = (4/3)πR3 = (4/3) × 3.14 × (7.0 × 108 m)3 = (4/3) × 3.14 × 3.43 × 1026 m3 = 1.44 × 1027 m3.
- Mean density ρ = M/V = 2.0 × 1030 kg / 1.44 × 1027 m3 = 1.4 × 103 kg m−3.
- Compare: density of water = 1.0 × 103 kg m−3; air at STP = 1.3 kg m−3. The Sun’s mean density, 1.4 × 103 kg m−3 = 1.4 g cm−3, is of the order of the density of liquids and solids, not of gases.
- Guess (‘gas-like’) is wrong: the mean density is about 1.4 times that of water and about 1000 times that of air.
| Substance | Density (kg m−3) | Class |
|---|---|---|
| Air (STP) | 1.3 | Gas |
| Water | 1.0 × 103 | Liquid |
| Sun (mean) | 1.4 × 103 | Comparable to liquids/solids |
| Iron | 7.9 × 103 | Solid |
| Lead | 1.13 × 104 | Solid |
Why is the density so high although the matter is a gas (plasma)? The Sun’s own enormous gravity compresses the matter: the pressure at the centre is about 1016 Pa, which keeps the particles close together despite the very high temperature (the gas pressure balances gravity). The matter is strongly ionised, so electrons and nuclei are separate and can be packed much more densely than in ordinary atoms. The density is not uniform: it is highest at the centre (about 105 kg m−3, much larger than the mean) and falls to about 10−4 kg m−3 near the surface, so 1.4 × 103 kg m−3 is only the average value (supplementary data, not from the NCERT text).
Extra depth. The test illustrates a lesson of the chapter: use the order of magnitude to judge the reasonableness of a result (Section 1.3). The mean density of the Earth is 5.5 × 103 kg m−3, so the Sun is about one quarter as dense as the Earth although it is 1.3 million times larger in volume. The mass of the Sun (2.0 × 1030 kg) is about 3.3 × 105 times the mass of the Earth (6.0 × 1024 kg).
Conclusion: The mean density of the Sun is about 1.4 × 103 kg m−3, in the range of densities of solids and liquids, not of gases, because of the huge gravitational compression.